A cell is the basic device comprising two electrodes separated
by an electrolyte. The name of the cell usually includes reference to
the materials used in the construction and the voltage of each cell
depends on the chemicals used, eg an Alkaline Manganese AA 1.5 V, or
a Lead-acid cell of about 2 V.
A battery is a collection of cells eg the PP3 9V (6 cells in
series) or the Lead-acid car battery (typically 12 V, also 6 cells).
Although the voltages are quoted usually as if they were accurate, mostly
they are not. Voltages vary according to many factors eg temperature
and state of charge.
There are 2 fundamental types of cells, Primary and Secondary.
Primary cells are meant to be used once only, through to the discharged
state and Secondary cells are designed to be recharged over and over
(typically several hundreds of times). Some chemistry is suitable for
use either as primary or secondary.
The number of different battery types, properties and applications is
enormous, quite apart from the fact that each type comes in a variety
of sizes, usually dictated by voltage and capacity. Capacity is measured
in ampere-hours (Ah) or thousandths of ampere hours (mAh).
The following comments give a resume of certain types, within the limits
of our knowledge, which you may wish to check with a definitive source
elsewhere.
Primary:
Zinc Carbon: nominal 1.5 V, an old type, cheap and voltage varies
considerably during use.
Alkaline Manganese: nominal 1.5V, ubiquitous replacement for
zinc-carbon, higher energy more expensive.
Mercury: phased out in many applications because mercury is
very poisonous, was/is used in small applications eg cameras, hearing
aids.
Lithium: a wide ranging family with voltages varying from 1.5
V to 3.6 V, high energy density, voltage almost constant and very long
shelf life. Sounds magic and indeed they are special but the downside
is that Lithium is a very reactive element which can lead to explosive
consequences. Do not attempt to charge unless explicitly specified and
avoid short circuits. They are also very expensive.
Zinc Air: nominal 1.4V, as its name suggests must be exposed
to the air (a seal is usually removed when first used), high self-discharge
rate.
Silver Oxide: nominal 1.55V. Often sold as button cells, for
use in calculators, cameras, watches etc where its stable discharge
characteristics are valuable.
Secondary:
Lead-acid: nominal 2 V per cell, as used in cars, well known
to be rechargeable, large capacities but lead is very poisonous.
Can be either wet or dry. Probably the easiest to recycle because the
large amount of lead in each battery has a value in the scrap metal
industry. Lead-acid and Sealed Lead-acid (SLA) are used where relatively
large energy ratings are called for but weight is not a major problem.
Nickel-Cadmium (Ni-Cd): 1.2 V per cell. Used extensively in rechargeable
situations and because it exhibits a memory effect is either continuously
trickle-charged or recharged after complete discharge (ie not partially
discharged and then charged). Ni-Cd can be recharged a large number
of times (say, more than a thousand), which may be the reason, unfortunately,
why they are so popular. Cadmium is very poisonous, it would
seem a good idea to avoid Ni-Cd wherever possible but has established
a track record and is quite common unfortunately.
Nickel Metal Hydride (NiMH): 1.2V per cell. They are a new generation
which can replace Ni-Cd and have higher energy density and longer life
cycle, and don't exhibit memory effect, are usually charged with constant-current
source. They do not contain the the most dangerous heavy metals so are
more environmentally friendly than Ni-Cd. We feel that NiMH batteries
should be used wherever possible to replace Ni-Cd. The disadvantage
is that they cannot be recharged so many times as Ni-Cd (maybe less
than a thousand), but unless you take care with the charge and recharge
discipline needed with Ni-Cd you may well finish up with a battery which
doesn't realise its potential and turns out to be inferior to NiMH (we
speak from experience).
Nickel-zinc: 7 cells for 12V, is claimed to provide the lowest
impact to the environment of any standard rechargeable battery technology
mainly because of the absence of contamination from the dangerous heavy
metals. They have lower cost than NiMH, are lighter and better performers
than lead acid, have a high capacity per cycle and high cycle life and
they also have low maintenance requirement. Size may be less than Lead-acid
and about the same as Ni-Cd. For a good reference see the Evercel
link on our Hazardous Waste page.
Lithium Ion (Li-Ion): used, as well as NiMH, in special applications
eg laptop computers, are expensive to produce and hence to buy. They
have the advantage that they have about twice the energy density of
Ni-Cd and around 50% more than NiMH hence can be much lighter and smaller
for the same capacity. They can be recharged for up to 1000 times approximately.
Lithium Polymer (LI-Polymer): apparently could become the battery
of the future. They are reputed to have similar characteristics to Li-Ion
but should be much cheaper to produce.
General Comments:
This has been one of the most difficult items to research. There
have been significant advances in battery technology over the past few
years and it is evident that the consumer culture has led to an increased
use. Undoubtedly batteries provide us with benefits and conveniences
which are valuable.
The battery market is a lucrative one and you can see that by surfing
the net, indeed the information provided seems to be very protective
of the market, with little to say, in the UK, about safe disposal. That
some batteries contain metals which are deadly dangerous to humans and
animals is undeniable; such dangers become reality when the items are
disposed of in standard waste rather than recycled in some way. All
this is compounded by the plethora of battery types (nothing to do with
sizes) so that it is difficult to identify the scale of the dangers.
Three heavy metals, present in batteries, namely
lead, cadmium and mercury pose serious health hazards.
The effects of these elements on animals (including humans) are terrible,
leading to debilitating pain with fatal consequences [for more detail
on the dangers see the WEEE synopsis in the Electrical/Electronic section].
Yet what do we do to prevent haphazard disposal of them? Sadly in the
UK, virtually nothing. We had expected the British Battery Manufacturers
Association (BBMA) to provide us with information that would allow easy
recycling. They have been active in setting up REBAT which purports
to be interested in recycling and sets targets but when we last looked
they suggested "in the first instance seek guidance from either
the distributor ..... or the battery manufacturer or the appliance manufacturer".
Sure, we good folks out here will do that, or maybe not be bothered.
There is a long list of battery recyclers but doubt if that will be
any use to the individual consumer. We are not impressed but decide
for yourself and pay a visit:
There are some minor recycling schemes, including experimental council
schemes. According to Which? (Feb 2003) Lancashire CC offers
a scheme and Bristol is trialling the first kerbside collection scheme.
Since Europe may aim for a 75% collection target by 2004 the UK has
a lot to do and hopefully many more councils will adopt the kerbside
approach (Oh, if only!). We have been pleased to note that some specialist
recycling takes place, for example CRL [see the Electrical section]
who recycle cellular 'phones, recycle the batteries contained therein.
Lead-acid car batteries are relatively well catered for because
they have an obvious scrap value (a substantial amount of lead) and
you could possibly collect money by taking them to the scrap metal dealer.
Local councils will usually take them for recycling.
Ni-Cd rechargeable batteries contain Cadmium and are increasingly
popular. In any piece of equipment they should be easily removable.
As long as they're being used they are not dangerous but if they are
dumped into landfill they are. Some firms will take them back in part
exchange but we have yet to find another convenient and reliable way
of disposal for the individual in the UK.
Mercury is used in miniature primary cells ( hearing aids, some
cameras). Certain hospitals and jewellers may take these for safe disposal.
You may also like to see our note about Mercury under the Fluorescent
Tubes heading in this section on Hazardous Waste.